Sample location images courtesy of Deborah Kelley (University of Washington)
Endeavour Ridge
48 ° 00
47 ° 57
47 ° 54
129 ° 05

Introduction

The big picture

Motivation for this project stems from recent interest in the global geochemical cycle of iron, due to revelations that fertilization of the surface ocean with iron may affect global climate (i.e. Peng and Broecker, 1991). While iron fertilization of high-nutrient, low-chlorophyll (HNLC) regions of the world's oceans such as the Southern Ocean and the equatorial Pacific Ocean may drawdown atmospheric carbon dioxide on short timescales (Cooper et al., 1996), it is unknown how fertilization will affect global climate over long timescales (Charette and Buesseler, 2000; Ridgwell, 2000). Of primary importance to this debate is the question of which iron sources (dust, slope sediments, hydrothermal fluids, and/or rivers) are most important to open ocean ecosystems and which would be primarily responsible for natural iron fertilization.

Black smokers, chimney morphology, and growth of deposits

Within the context described above, this project examines iron in sulfide minerals in a deep-sea hydrothermal vent chimney, or "black smoker". The chimney under consideration, called "Finn", is from the Mothra vent field along the Endevour segment of the Juan de Fuca ridge, Pacific Ocean.

Hannington et al. (1995) describe growth rates for black smokers as high as ten centimeters per day, with individual chimney lifetimes anywhere from days to decades. It is noted, though, that hydrothermal activity in any particular field can persist for several thousands of years.

The metals, including iron, found in chimney structures represent a small proportion of the total metals released from the vent. According to Hannington et al. (1995), at least 90% of the metals in the hydrothermal vent solution is lost in the buoyant vent plume. In addition, since particles less than fifty microns comprise as much as 99% of the plume, these metals are normally dispersed more than one kilometer from the vent source. This distance is usually much greater than the one hundred meter radial extent characteristic of a depositıs debris apron.

As a result of these processes, the iron analyzed in Finn represents a small fraction of the total iron that is released into the black smoker complex from sub-crustal levels. In addition, it should be noted that the bulk of the iron in the fluid derives from alteration of oceanic crust or from magmatic sources. The concentration of iron in seawater (around the picomolar range) is extremely low compared to rocks (ppm) and is assumed to be a minor component in these systems.



Based on figure from Hannington et al. (1995) Physical and chemical processes of seafloor mineralization at mid-ocean ridges. In Seafloor hydrothermal systems: physical, chemical, biological, and geological interactions. Humphris, S. et al. [eds]. Geophysical Monograph 91 (Geophysical Monograph Series), American Geophysical Union: 115-157.




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